Synthesis and structures of monomeric divalent germanium and tin compounds containing a bulky diketiminato ligand

eaction of the beta -diketiminato lithium salt Li(OEt2) [HC(CMeNAr)(2)] (AT = 2,6-i-Pr2C6H3) with GeCl2. (dioxane) and SnCl2 in diethyl ether provided the monomeric complexes [HC-(CMeNAr)(2)]MCl (M = Ge (2), Sn (3), respectively) with a three-coordinated metal center. The reductive dehalogenation reactions of 3 with C8K and LiAlH4 afforded [HC(CMeNAr)(2)](2)Sn (7) and [HC(CMeNAr)(2)]AlH2, respectively. The metathesis reactions of 3 with t-BuLi, AgSO3CF3, and NaN3 resulted in the formation of [HC(CMeNAr)(2)]Sn(t-Bu) (4), [HC(CMeNAr)(2)]-Sn(OSO2CF3) (5), and [HC(CMeNAr)(2)]SnN3 (6), respectively. Compounds 2, 3, 5, and 7 were characterized by single-crystal X-ray structural analysis. The structures indicate that the beta -diketiminato backbone is essentially planar and the metal centers reside in distortedtetrahedral environments with one vertex occupied by a lone pair of electrons. The bond angles at the metal center are in the range 85.2(8)-106.8(2)degrees, and the most acute angle is associated with the bite of the chelating ligand.