期刊
BIOCHEMICAL SYSTEMATICS AND ECOLOGY
卷 44, 期 -, 页码 53-60出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.bse.2012.04.008
关键词
Sea cucumbers; Eupentacta fraudatrix; 4,4,14-Trimethylsterol oligoglycosides; Biosynthesis
资金
- Presidium of the Russian Academy of Science
- President of the Russian Federation Program for Support of the Leading Scientific Schools [3531.2010.4]
- State Contract of the Russian Federation [02.740.11.0777]
- FEB RAS for young scientists [11-III-B-05-084]
- RFBR [11-04-00052-a, 11-04-00480-a]
A novel oligoglycoside cucumarioside A(8) with unprecedented hydroxy group at C-18 was isolated from sea cucumber Eupentacta fraudatrix and its structure elucidated. The presence of hydroxy group at C-18 indicates that the glycoside is a hot metabolite that allows clarification of some peculiarities of 4.4,14-trimethylsterol glycoside biosynthetic pathways. A hypothetical scheme of biosynthesis of triterpene glycosides in sea cucumbers is proposed where direct formation of lanostane derivatives with a 7(8)-double bond from prosteroid cation is possible. (C) 2012 Elsevier Ltd. All rights reserved.
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