期刊
POLYHEDRON
卷 20, 期 7-8, 页码 669-673出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0277-5387(01)00731-8
关键词
diiron(III) complexes; crystal structures; magnetic properties
A new dialkoxo-bridged diiron(III) complex, [Fe-2(N-3)(2)(L)(2)](ClO4)(2) (1) [HL = bis(benzimidazol-2-ylmethyl)(2-hydroxyethyl)amine], was synthesized and characterized. According to X-ray crystallographic studies on the solvated species 1 . 2C(2)H(5)OH, each Fe(III) ion lies in a highly distorted octahedral environment, and two Fe(III) ions are bridged by the ethoxyl oxygens from two L ligands. Cryomagnetic analyses indicated a moderate antiferromagnetic interaction between the high-spin Fe(III) ions, with J = -21.3 cm(-1). (C) 2001 Elsevier Science B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据