期刊
APPLIED PHYSICS LETTERS
卷 78, 期 16, 页码 2360-2362出版社
AMER INST PHYSICS
DOI: 10.1063/1.1358847
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This letter reports the ferroelectric and electromechanical properties of a class of ferroelectric polymer, poly (vinylidene-fluoride-trifluoroethylene-chlorotrifluoroethylene) terpolymer, which exhibits a slim polarization hysteresis loop and a high electrostrictive strain at room temperature. The dielectric and polarization behaviors of this terpolymer are typical of the ferroelectric relaxer. The x-ray and Fourier transform infrared results reveal that the random incorporation of bulky chlorotrifluoroethylene (CTFE) ter-monomers into polymer chains causes disordering of the ferroelectric phase, Furthermore, CTFE also acts as random defect fields which randomize the inter- and intrachain polar coupling, resulting in the observed ferroelectric relaxer behavior. (C) 2001 American Institute of Physics.
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