期刊
TETRAHEDRON LETTERS
卷 42, 期 16, 页码 3033-3036出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00363-X
关键词
nitrones; phosphonates; enzyme inhibitors; peptide mimetics; stereoselective synthesis; aminophosphonation
The addition reaction of diethyl phosphite to O-silylated N-benzyl nitrones derived from chiral alpha -alkoxy and N-Boc alpha -amino aldehydes has been studied as a stereoselective carbon-phosphorus bond forming process for the synthesis of polyhydroxylated alpha -amino and alpha,beta -diamino phosphonates. Key intermediates are the corresponding N-hydroxy alpha -amino phosphonates. (C) 2001 Elsevier Science Ltd. All rights reserved.
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