期刊
TETRAHEDRON LETTERS
卷 42, 期 16, 页码 2931-2932出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00336-7
关键词
carbamoylsilane; siloxyaminocarbene; carbamoylsilylation
A carbamoylsilane behaves as a siloxyaminocarbene towards electrophilic reagents, undergoing C-H insertion with chloroform, methyl propiolate and 1-chloro-2,4-dinitrobenzene. Its reaction with DMAD results in carbamoylsilylation. (C) 2001 Published by Elsevier Science Ltd.
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