期刊
CHEMICAL SOCIETY REVIEWS
卷 30, 期 3, 页码 158-167出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b008101i
关键词
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This review emphasizes recent or pertinent efforts to create functional plasticity with artificial barrel-stave supramolecules and related motifs. On the structural level, a summary of engineered, de novo designed, and artificial beta -barrels beyond peptide chemistry is followed by representative alpha -helix bundles and barrel-stave supramolecules comprising oligonucleotides, inorganic architecture, and organic barrel-stave ion channel models. On the functional level, selected examples are given to highlight divers aspects of molecular recognition, translocation, and transformation that are currently accessible with artificial barrel-stave supramolecules.
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