期刊
JOURNAL OF SOLUTION CHEMISTRY
卷 30, 期 5, 页码 475-487出版社
KLUWER ACADEMIC/PLENUM PUBL
DOI: 10.1023/A:1010304732665
关键词
solvation; solution; thermodynamics
The quantities, now referred to as Solvation Thermodynamics, have evolved from their predecessors, the standard thermodynamics of solution. While the former are defined for a molecular process of solvation, the latter were based on a macroscopic thermodynamic process. It is shown that the solvation Gibbs energy, DeltaG(s)(*) is the only genuine measure of the average free energy of interaction of a single (solute) molecule with its surroundings. Some of the other advantages of DeltaG(s)(*) and its derived quantities are also discussed.
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