期刊
PHYSICAL REVIEW LETTERS
卷 86, 期 19, 页码 4314-4317出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.86.4314
关键词
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LiMn2O4 has been studied using magic-angle-spinning nuclear magnetic resonance (MAS NMR). 1D MAS NMR shows three Li resonances assigned to different crystallographic sites. At low temperatures an extra peak appears, indicating charge ordering of Mn3+ and Mn4+. Direct observation of the lithium dynamics was possible using rotor-synchronized 2D exchange NMR. A millisecond time scale exchange of lithium starts around 285 K between the 8a and the 16c site. At 380 K lithium even starts to hop between more than two sites. The activation energies and Li jump rates are derived and are in agreement with those determined macroscopically.
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