期刊
INORGANICA CHIMICA ACTA
卷 316, 期 1-2, 页码 1-6出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0020-1693(01)00310-3
关键词
dioxocompounds; oxo-transfer agent; 1,2-addition
A new dioxodithiocarbamato compound of molybdenum(VI), MoO2(S2CNC4H8)(2) (1), has been prepared and its reactivity towards substituted silanes, R3SiX (for R = Me, and X = Cl, Br, NCS, SO3Cl; R = n-Bu, X = Cl), HClO4 and PPh, has been studied. The structure of 1 was determined by X-ray analysis. The oxygenation capacity of 1 towards tertiary aryl phosphines was evaluated by P-31 NMR spectroscopy, and changes at the oxomolybdenum moiety were monitored by UV-V is spectrophotometry. (C) 2001 Elsevier Science B.V. All rights reserved.
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