期刊
JOURNAL OF CHEMICAL PHYSICS
卷 114, 期 20, 页码 8926-8931出版社
AMER INST PHYSICS
DOI: 10.1063/1.1361251
关键词
-
The first rotationally resolved high resolution excitation spectrum of RbCs is obtained near 520 nm by resonance enhanced two photon ionization study. The excited electronic state is assigned to the 5 (1)Sigma (+) state by the spectrum analysis and comparison with ab initio calculations. The spectroscopic constants of the 5 (1)Sigma (+) state are determined to be T-e = 18 564.560(76) cm(-1), omega (e) = 39.193(25) cm(-1), R-e = 4.951(5) Angstrom. The Rydberg-Klein-Rees potential curve is constructed and compared with theoretical calculations. Avoided crossings between the 5 (1)Sigma (+) and 6 (1)Sigma (+) states of RbCs are observed. (C) 2001 American Institute of Physics.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据