期刊
TETRAHEDRON
卷 57, 期 22, 页码 4691-4698出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(01)00418-5
关键词
Illicium; sesquiterpene; structure; synthesis; anislactone; merrilactone
Two new anislactone-type sesquiterpenes, merrilactones B (1) and C (2) were isolated from the pericarps of Illicium merrillianum along with anislactones A (4) and B (5). Their structures were elucidated by spectroscopic methods and chemical transformation and the structure of merrilactone C was established by X-ray crystallographic analysis of its methyl derivative. Merrilactone A (3), a unique anislactone-type sesquiterpene showing neurite outgrowth promoting activity, was effectively synthesized from anislactone B. (C) 2001 Elsevier Science Ltd. All rights reserved.
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