期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 123, 期 21, 页码 4951-4959出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja010108u
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Electron donor/acceptor (EDA) interactions are found to be a versatile methodology for the engineering of reactive heteromolecular crystals. In this way, a series of the charge-transfer pi -complexes between bis(alkylimino)-1,4-dithiin accepters and anthracene donors are shown to form heteromolecular(l:l)crystalline solids that spontaneously undergo stereoselective [2 + 4] Diels-Alder cycloadditions. The flexible nature of the 1.4-dithiin moiety allows this homogeneous topochemical transformation to proceed with minimal distortion of the crystal lattice As a result, a unique (single) crystal phase of the Dials-Alder adduct can be produced anti-thermodynamically with a molecular arrangement very different from that in solvent-grown crystals. Such a topochemical reaction between bis(methylimino)- 1,4-dithiin and anthracene proceeds thermally and homogeneously up to very high conversions without disintegration of the single crystal. This ideal case of the mono-phase topochemical conversion can be continuously monitored structurally (X-ray crystallography) and kinetically (NMR spectroscopy) throughout the entire range of the crystalline transformation. The resultant artificial crystal of the Diels-Alder adduct is surprisingly stable despite its different symmetry and packing mode compared to the naturally grown (thermodynamic) crystal.
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