期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 505, 期 1-2, 页码 170-172出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-0728(01)00477-6
关键词
corrole; oxidation; protonation; spectro-electrochemistry
Octaethylcorrole (H3OEC) has been studied electrochemically in methylene chloride. In contrast with what is commonly observed in tetrapyrrolic macrocycles, no radical cation was detected after a one-electron oxidation. Instead, the protonated species [H4OEC](+) was obtained. [H4OEC](+) was easily converted back to the initial corrole by electrochemical reduction. (C) 2001 Elsevier Science B.V. All rights reserved.
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