Effect of sediment pH on resuspension of kaolinite sediments

The resuspension of contaminated cohesive sediments can impact water quality by mobilizing sediment particles and adsorbed contaminants. Changes in psysicochemical and electrochemical environments, around resuspended sediment particles, may cause some contaminants to desorb into the water column. The contribution of contaminated sediments to degradation of water quality depends on an estimate of sediment resuspension rates. In this study, the resuspension of Georgia kaolinite sediments under varying pH conditions was investigated in laboratory flume experiments. Because the edge charge of kaolinite particles is pH dependent, kaolinite particles exhibit different modes of particle associations under varying pH conditions. The paper characterizes these particle associations and relates them to the resuspension of kaolinite sediments for varying pH values. Variations in sediment water content, changes from a stratified to a uniform sediment bed, changes in rheological properties, and variations in the electrophoretic mobility of kaolinite particles were all indicative of the changes in particle associations that resulted from changes in sediment pH. The critical shear stress and the erosion rate coefficient were evaluated for varying pH values and explained by particle associations. A rheometer was used to measure rheological properties of the settled sediment bed; the measured yield stresses had a direct correlation with critical shear stresses.