期刊
TETRAHEDRON
卷 57, 期 26, 页码 5527-5532出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(01)00478-1
关键词
diaryl ethers; diaryls; electrochemical reaction; phenolic oxidation
Anodic oxidation of simple o-halogenated phenol derivatives has been investigated. Among the oxidation products, tricyclic ketone 9 was obtained, along with both the corresponding diaryl ethers 3 and 4 and the diaryls 5-8. Additionally, the effect of the alkyl substituent on the oxidation mode was inspected: anodic oxidation of phenols carrying n-propyl or 3-hydroxylpropyl groups 10b and 10c mainly provided the dienone compounds 11 and 15 through two-electron oxidation. (C) 2001 Elsevier Science Ltd. All rights reserved.
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