[GRAPHICS] Addition of a variety of arylboronic acids to peracetylated glycals takes place in the presence of a catalytic amount of Pd(OAc)(2). The reaction involves the syn addition of a sigma -aryl-Pd complex to the glycal double band followed by anti elimination of Pd(OAc)(2) to provide a carbon-ferrier type product, This method provides a practical and convenient stereoselective synthesis of C-arylglycosides.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据