期刊
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
卷 31, 期 6, 页码 983-995出版社
TAYLOR & FRANCIS INC
DOI: 10.1081/SIM-100105255
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Ruthenium(II) carbonyl complexes have been synthesised by reacting [RuH2(CO)(PPh3)(3)] or [RuHCl(CO)(PPh3)(2)(Z)] (Z = PPh3, pyridine (py) or piperidine (pip)) with tridentate Schiff base ligands derived by condensing salicylaldehyde, o-vanillin or o-hydroxyacetophenone with N(4)-phenylsemi-carbazide. These complexes have been characterised by analytical, IR, electronic, H-1 NMR and P-31 NMR spectral studies. The complexes of the general formula [Ru(L) (CO)(PPh3)(Z)] (L = Schiff base anion; Z = PPh3, py or pip) tentatively have been assigned an octahedral structure. Some of the complexes have been tested for in vitro growth inhibitory activity against the bacteria Escherichia coli, Bacillus sp. and Pseudomonas sp.
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