期刊
ACCOUNTS OF CHEMICAL RESEARCH
卷 34, 期 7, 页码 571-581出版社
AMER CHEMICAL SOC
DOI: 10.1021/ar010003w
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X-ray absorption fine structure (XAFS) measurements unambiguously establish the structure of the active centers in highperformance Ti-SiO2 epoxidation catalysts. Subtleties in structural changes in proceeding from the dispersed titanocene dichloride precursor to the anchored Ti-IV centers are charted, in situ, by both near-edge (XANES) and extended-edge (EXAFS) measurements. The active centers are tripodally attached titanol groups: (Si-O)(3)-TiOH. These permit facile expansion of the coordination shell (also monitored by in situ XAFS studies) during catalysis, and thereby lead to the formulation of a plausible mechanism of epoxidation of alkenes that is consonant with recent DFT computations. Previously proposed mechanisms, based on a three-coordinated titanyl group (as well as possible five- or six-coordinated active sites), are discounted. Comparable XAFS studies of soluble catalytically active four-coordinated Ti-IV-containing molecular entities establish that the heterogeneous Ti-SiO2 catalyst has single-site active centers. Equipped with such information, minute changes in hydrophobicity and local composition (e.g., replacement of one Si by a Ge) can be wrought so as to boost the performance of the catalyst. The merits of using combined in situ X-ray absorption spectroscopic and X-ray diffractometric measurements are also highlighted.
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