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Conical intersections: The new conventional wisdom

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JOURNAL OF PHYSICAL CHEMISTRY A
卷 105, 期 26, 页码 6277-6293

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AMER CHEMICAL SOC
DOI: 10.1021/jp003731u

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During the past decade the perception of conical intersections has changed. It is now appreciated that what was once viewed largely as a theoretical curiosity is an essential aspect of electronically nonadiabatic processes. Concomitantly, our understanding of this singular consequence of the Born-Oppenheimer separation of nuclear and electronic motion has grown enormously. In this work the theory of conical intersections is reviewed.

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