期刊
TETRAHEDRON
卷 57, 期 28, 页码 5967-5974出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(01)00555-5
关键词
aryl halides; arylation; carbonyl compounds; palladium and compounds
Alkyl (ethyl to butyl) aryl ketones have been found to undergo multiple arylation on the alkyl chains accompanied by oxidative unsaturation upon treatment with excess aryl bromides in the presence of a palladium catalyst and a base. In the case of phenyl propyl ketones, for example, the arylation occurs up to five times on the alpha -and gamma -positions as well as the ortho-position of the phenyl ring to give 1-(biphenyl-2-yl)-2,4,4,4-tetraphenyl-2-buten-1-ones along with other arylation products. A number of alpha,beta -unsaturated carbonyl compounds are also arylated multiply on the alpha- and gamma -positions. (C) 2001 Elsevier Science Ltd. All rights reserved.
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