期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 507, 期 1-2, 页码 75-81出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-0728(01)00387-4
关键词
alkenes; asymmetric induction; epoxidation; electrochemical reaction; manganese compounds
Enantioselective electro-epoxidation of olefins by using an optically active Mn-salen complex, (S,S)-N,N ' -bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III)chloride (3), as a mediator in a CH2Cl2 aqueous NaCl two-phase system was performed successfully in a simple undivided cell under constant current conditions. Optimization of the electrolysis conditions and estimation of the reaction mechanism are discussed. (C) 2001 Elsevier Science B.V. All rights reserved.
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