期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 66, 期 14, 页码 4766-4770出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo000463n
关键词
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The omega -alkynals yielded macrocyclic (S)-allylic alcohols in a one-pot reaction sequence involving alkyne monohydroboration, boron to zinc transmetalation, and ((+)-DAIB)-catalyzed enantioselective intramolecular ring closure to the aldehyde function. A general study of this macrocyclization methodology is presented with respect to ligand type, size, and nature of the formed rings.
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