TGA modeling of the thermal decomposition of CCA treated lumber waste

To guide the development of thermal decomposition methods for disposal of CCA treated wood, reactions during the thermal decomposition of CCA treated wood were modeled using thermogravimetric analysis (TGA), with special focus placed on arsenic volatilization. Simple inorganic compounds, such as As2O5, CuO, and Cr2O3, were used to model the thermal behavior of the inorganics in CCA treated wood. In air and nitrogen, arsenic (V) oxide began to volatilize at 600 degreesC during temperature ramps at 5 degreesC/min. During a 5 degreesC/min ramp in a hydrogen mix, arsenic (V) oxide began decomposition at 425 degreesC. Arsenic volatile loss from CCA treated wood can depend strongly on the gases produced by wood thermal decomposition. In the presence of As2O5, chromium (III) oxide and copper (II) oxide formed arsenates in air and nitrogen. Chromium arsenates began decomposition as low as 790 degreesC. This suggested that chromium arsenates in CCA treated wood formed during original preservative fixation may decompose as low as 790 degreesC. Copper arsenates were stable up to 900 degreesC in air, but showed only a limited range of stability in nitrogen. Depending on process conditions, the formation of copper arsenates may limit arsenic loss during thermal decomposition of CCA treated wood up to 900 degreesC. The thermal decomposition of inorganic oxides was influenced by interactions with wood and wood decomposition products. In a dry YP sawdust/As2O1 mix, arsenic (V) oxide volatilized at 370 degreesC during inert pyrolysis at 5 degreesC/min and at 320 degreesC during smoldering combustion at 5 degreesC/min. Thermal dwells of a dry YP/As2O5 Mix showed no arsenic loss at 250 degreesC, but significant loss occurred during higher temperature dwells. During inert pyrolysis at 5 degreesC/min, the formation of complexes and hydrates were shown to prevent arsenic loss up to 400 degreesC.