期刊
SYNTHESIS-STUTTGART
卷 -, 期 10, 页码 1453-1455出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2001-16089
关键词
epoxides; ketones; cyclopropanes; oxidations; transition metals
A number of aliphatic and arylaliphatic alpha,beta -epoxy ketones were prepared in good yields in a one-pot procedure by a manganese-catalyzed ring cleavage of I-substituted and 1,2-disubstituted cyclopropanols with oxygen followed by dehydration of the resulting cyclic peroxides with alkali.
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