期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 10, 期 -, 页码 449-458出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.10.42
关键词
2-alkynylanilines; fluorination; gold catalysis; indoles; tandem reactions
资金
- Universita dell'Aquila
- Ministsre de l'Education et de la Recherche
- Centre National de la Recherche Scientifique (CNRS)
The scope and limitations of gold-catalyzed tandem cycloisomerization/fluorination reactions of unprotected 2-alkynylanilines to have access to 3,3-difluoro-2-aryl-3H-indoles and 3-fluoro-2-arylindoles are described. An unprecedented aminoauration/oxidation/ fluorination cascade reaction of 2-alkynylanilines bearing a linear alkyl group on the terminal triple bond is reported.
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