期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 10, 期 -, 页码 1261-1266出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.10.126
关键词
allylic substitution; enantioselectivity; ferrocene; organophosphorus; palladium; regioselectivity
资金
- National Basic Research Program of China (973 Program) [2010CB833300]
- National Natural Science Foundation of China [21025209, 21121062, 21332009]
- Chinese Academy of Sciences
A class of novel, easily accessible and air-stable 1-[bis(trifluoromethyl)phosphine]-1'-oxazolinylferrocene ligands has been synthesized from ferrocene. It became apparent that these ligands can be used in the regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates in a highly efficient manner. Excellent regio- and enantioselectivity could be obtained for a wide range of substrates.
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