期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 10, 期 -, 页码 271-275出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.10.22
关键词
cyclic phosphonium; ionic liquid; organophosphorus; phosphinanium; phospholanium; phosphonium
资金
- City University of New York Energy Institute
- Professional Staff Congress of the City University of New York (PSC-CUNY) Research Award Program [43]
- U. S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences Geosciences and Biosciences [DE-AC02-98CH10886]
Ionic liquids (ILs) incorporating cyclic phosphonium cations are a novel category of materials. We report here on the synthesis and characterization of four new cyclic phosphonium bis(trifluoromethylsulfonyl)amide ILs with aliphatic and aromatic pendant groups. In addition to the syntheses of these novel materials, we report on a comparison of their properties with their ammonium congeners. These exemplars are slightly less conductive and have slightly smaller self-diffusion coefficients than their cyclic ammonium congeners.
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