期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 10, 期 -, 页码 2484-2500出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.10.260
关键词
carbon dioxide; carboxylic acids; counter electrode reaction; electrocarboxylation mechanism; reactor setup
资金
- Industrieel Onderzoeksfonds KU Leuven [IKP/10/005]
- KU Leuven through the Methusalem grant CASAS, in the frame of IAP 7 Supramolecular Chemistry and Catalysis
The near-unlimited availability of CO2 has stimulated a growing research effort in creating value-added products from this greenhouse gas. This paper presents the trends on the most important methods used in the electrochemical synthesis of carboxylic acids from carbon dioxide. An overview is given of different substrate groups which form carboxylic acids upon CO2 fixation, including mechanistic considerations. While most work focuses on the electrocarboxylation of substrates with sacrificial anodes, this review considers the possibilities and challenges of implementing other synthetic methodologies. In view of potential industrial application, the choice of reactor setup, electrode type and reaction pathway has a large influence on the sustainability and efficiency of the process.
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