期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 9, 期 -, 页码 852-859出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.9.98
关键词
aziridines; catalytic; heterocycles; palladium; ring opening
资金
- EPSRC
- University of Reading
- AstraZeneca
- Royal Society
- Parke Davis Neuroscience Research Centre (Cambridge, UK)
- Nuffield Foundation
Predominantly (E)-N-diphenylphosphinyl vinyl aziridines are prepared by a reaction of N-diphenylphosphinyl imines with alpha-bromoallyllithium in the presence of freshly fused ZnCl2. These aziridines undergo a ring-opening reaction with a variety of carbon and heteronucleophiles, in good yield, and generally with good regioselectivity.
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