期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 4, 期 8, 页码 384-387出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S1387-7003(01)00221-0
关键词
cadmium; one-dimensional coordination polymer; 4-sulfobenzoate; hydrothermal synthesis
The hydrothermal reaction of cadmium hydroxide with 4-sulfobenzoic acid and 2,2 ' -bipyridine yields ID coordination polymer [Cd-2(L)(2)(2,2 ' -bipy)(2)(H2O)(2))(n) 1 (where L = 4-sulfobenzoic acid), with blue fluorescent emission in which each [Cd-2(L)(2)(2, 2 ' -bipy)(2) (H2O)(2)] unit tan approximate rectangular molecular box) is linked together by Il, carboxylate to result in the formation of 1D chain coordination polymer. Crystal data for 1: triclinic, space group P-1(No.2), a = 8.8350(16), b = 9.4770(16), c = 11.8019(15) Angstrom; alpha = 99.174(11), beta = 105.776(13). gamma = 113.718(15)degrees: V = 829.1(2) Angstrom (-3); Z = 2: R-1 = 0.0206. wR(2) = 0.0526 for 2925 independent reflections with l > 2 sigma (1). (C) 2001 Elsevier Science B.V. All rights reserved.
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