期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 7, 期 -, 页码 1584-1601出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.7.187
关键词
ate complex; catalytic direct arylation; mechanism; oxazole; selectivity; transition-metal catalysis
Catalytic direct (hetero)arylation of (hetero)arenes is an attractive alternative to traditional Kumada, Stille, Negishi and Suzuki-Miyaura cross-coupling reactions, notably as it avoids the prior preparation and isolation of (hetero)arylmetals. Developments of this methodology in the oxazole series are reviewed in this article. Methodologies, selectivity, mechanism and future aspects are presented.
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