期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 7, 期 -, 页码 892-896出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.7.102
关键词
C-H functionalisation; gold catalyst; halide abstraction; N-heterocyclic carbene; silver salt; substrate activation
资金
- EPSRC
- ERC
- Royal Society
- EPSRC [EP/H015418/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H015418/1] Funding Source: researchfish
The role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C-H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given.
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