期刊
TETRAHEDRON
卷 57, 期 33, 页码 7143-7148出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(01)00683-4
关键词
coupling reactions; fluorine and compounds; hypervalent elements
1-Fluoro-1,3-enynes were stereoselectively prepared by the cross-coupling reaction of 1-alkynes with beta -fluoroalkenyliodides obtained from (beta -fluoroalkenyl)iodonium salts. As the reaction proceeds under mild conditions, polyfunctionalized 1-fluoro-1,3-enynes could be prepared, and the synthesis of a fluorinated analog of a natural compound was achieved using this method. (C) 2001 Elsevier Science Ltd. All rights reserved.
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