期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 16, 页码 1452-1453出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b103447m
关键词
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The first enantioselective synthesis of 12-tert-butyl substituted 7,8-dihydrobenzo[c]phenanthrene-1,4-quinones having helical chirality is achieved with good chemical and optical yields through a domino Diels-Alder reaction-sulfoxide elimination-oxidation process starting from enantiopure (S)-2-(p-totylsulfinyl)-1,4-benzoquinone and 5-tert-butyl substituted 3-vinyl-1,2-dihydronaphthalenes as dienes.
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