期刊
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY
卷 65, 期 9, 页码 2065-2069出版社
TAYLOR & FRANCIS LTD
DOI: 10.1271/bbb.65.2065
关键词
marine natural product; methyl-branched fatty acid; optically active fatty acid; Plakinastrella sp.; sponge
The (R)-enantiomer (1) of methyl (5Z,9Z)-17-methyl-nonadeca-5,9-dienoate, the structure proposed for a metabolite of the Philippine sponge, Plakinastrella sp., was synthesized. The H-1- and C-13-NMR spectra of the synthetic material were different from those reported for the natural product. The proposed structure 1 is therefore incorrect.
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