期刊
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
卷 27, 期 9, 页码 619-621出版社
MAIK NAUKA/INTERPERIODICA
DOI: 10.1023/A:1017989219486
关键词
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The reactions of salts formed by the B10H102- anion with carboxylic acids were studied. From the model systems Cat(2)B(10)H(10) + HCOOH (Cat = Et4N+, Bu4N+, Ph4P+, Ph4As+), several intermediates were isolated and characterized. A mechanism was proposed for the replacement of the exo-polyhedral hydrogen atoms in B10H10 by carboxylate groups in the reactions of Cat(2)B(10)H(10) with carboxylic acids.
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