期刊
TETRAHEDRON LETTERS
卷 42, 期 36, 页码 6365-6368出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)01283-7
关键词
carboranes; conformation; molecular design
Compounds (1-3), which are composed of benzene nuclei linked through 1,2-dicarba-closo-dodecaborane (o-carborane), were synthesized and their structures were determined by X-ray crystallography. 1,3-Bis(2-phenyl-o-carboran-1-yl)benzene and 1,3,5-tris(2-phenyl-o-carboran-1-yl) benzene (3) have syn stereochemistry of all the terminal benzene rings, despite their steric overcrowding. (C) 2001 Elsevier Science Ltd. All rights reserved.
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