期刊
ORGANIC LETTERS
卷 3, 期 18, 页码 2811-2814出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol0101178
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资金
- NCI NIH HHS [CA77284, CA53913] Funding Source: Medline
[GRAPHICS] Tallysomycins are glycopeptide antibiotics that were first isolated from fermentation broths of Streptoalloteichus hindustanus. They are structurally related to the bleomycins but contain an additional talose sugar attached via a unique glycosylcarbinolamide linkage. Herein we report the synthesis of a key tallysomycin intermediate that incorporates the glycosylcarbinolamide moiety unique to the tallysomycins.
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