期刊
CARBOHYDRATE RESEARCH
卷 334, 期 4, 页码 327-335出版社
ELSEVIER SCI LTD
DOI: 10.1016/S0008-6215(01)00181-1
关键词
stereospecific synthesis; beta-D-allopyranoside; dihydroxylation; beta-D-erythro-2,3-Dideoxyhex-2-enopyrano sides; inversion of configuration
The synthesis of 4,6-O-benzylidene-beta -D-erythro-2-3-dideoxyhex-2-enopyranosides and their osmium and ruthenium catalysed dihydroxylation reactions have been investigated. These reactions have been shown, for a range of monosaccharides and a disaccharide, to proceed stereospecifically to give beta -D-allopyranosides in moderate to excellent yield. (C) 2001 Published by Elsevier Science Ltd.
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