期刊
TETRAHEDRON LETTERS
卷 42, 期 37, 页码 6519-6522出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)01296-5
关键词
xanthenoic ester; xanthenoate; photo-fragmentation; xanthene radical; formyl radical; lactonisation; lactone
In the context of our work on photocleavable fragrance precursors, we have discovered a new photo-fragmentation of xanthenoic esters into xanthene- and formyl radicals. This homolytic cleavage has not been reported previously. Thus, unsaturated formyl radicals cyclise to lactones of various ring size. (C) 2001 Elsevier Science Ltd. All rights reserved.
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