期刊
ORGANIC LETTERS
卷 3, 期 19, 页码 3009-3012出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol016420q
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资金
- NCRR NIH HHS [1S10-RR-04870] Funding Source: Medline
- NIGMS NIH HHS [GM 33328-18] Funding Source: Medline
[GRAPHICS] The synthesis of (-)-epibatidine has been accomplished utilizing a highly exo-selective asymmetric hetero Diels-Alder reaction. The key steps employed to transform the resulting bicycle into the natural product include a fluoride-promoted fragmentation and a Hofmann rearrangement.
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