期刊
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS
卷 40, 期 10, 页码 5999-6002出版社
INST PURE APPLIED PHYSICS
DOI: 10.1143/JJAP.40.5999
关键词
piezoelectrics; morphotropic phase boundary; perovskite; tolerance factor; Curie temperature; Bi perovskite; lead titanate; ceramics
New morphotropic phase boundary (MPB) piezoelectrics, with ferroelectric phase transition (T-c) exceeding that of PbZrO3-PbTiO3 (PZT), were investigated. Based on a perovskite tolerance factor-T-c relationship, new high T-c MPB systems were projected in the Bi(MC)O-3-PbTiO3 system, where Me is a relatively large B+3-site cation. For the (1 - x)BiScO3-(x)PbTiO3 solid solution, a MPB was found at x-0.64 separating the rhombohedral and tetragonal phases, with correspondingly enhanced dielectric and piezoelectric properties. A transition temperature T-c of similar to 450 degreesC was determined with evidence of T-c's on the order of greater than or equal to 600 degreesC in the BiInO3 and BiYbO3 analogues, though issues of perovskite stability remain for the smaller tolerance end-member systems.
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