期刊
TETRAHEDRON LETTERS
卷 42, 期 40, 页码 6983-6986出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)01471-X
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S-1, Ar-type reactions of various heterocycles with ortho-substituted (1'S,P)-tricarbonyl[(1-chloroethyl)-eta (6)-benzene]chromium(0) derivatives lead to a family of novel planar chiral bidentate and pseudo-bidentate ligands. Two members of this family (1'S.P)-2-[1'-tricarbonyl-eta (6)-((2-P,P-diphenylphosphino)phenyl)-chromium(0))ethyl] furan and thiophene show high activity and enantioselectivity in the Pd-catalyzed hydrosilylation of styrenes. (C) 2001 Published by Elsevier Science Ltd.
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