The rational and high-yield synthesis of [(COD)Rh{(eta (2)-BH3)Ph2PCH2PPh2}][PF6] (1), which bears a chelating monoborane phosphine, is reported; the solid-state structure shows that the borane coordinates to the metal via two 2e-3c B-H-Rh bonds, which in solution at room temperature are fluxional between all three B-H bonds. Complex 1 is isolated as an air-stable crystalline salt, and its applicability as a catalyst in organic synthesis has been demonstrated in the coupling of boronic acids with enones.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据