期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 66, 期 21, 页码 7008-7012出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo015709i
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Synthetic procedures for monoazathiacrown ethers were explored, and monoazatrithia-12-crown-4, monoazatetrathia-15-crown-5, and monoazapentathia-18-crown-6 were obtained in moderate yields by the reaction of bis(2-chloroethyl)amine with the appropriate dithiols in the presence of lithium hydroxide in THF. To evaluate metal-ion binding properties of the monoazathiacrown ethers by solvent extraction, lipophilic dodecyl and dodecanoyl groups were incorporated onto the monoazathiacrown ethers. The solvent extraction experiments suggested that monoazathiacrown ethers have Ag+ and Hg2+ selectivities and that the relative selectivity between Ag+ and Hg2+ depends on their nitrogen atom properties and numbers of sulfur atoms reflecting the respective affinities of nitrogen and sulfur atoms to Hg2+ and Ag+. An interesting ability to bind Mg2+ was observed in the case of N-dodecyl monoazatrithia-12-crown-4.
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