期刊
JOURNAL OF BIOMOLECULAR NMR
卷 21, 期 3, 页码 263-268出版社
KLUWER ACADEMIC PUBL
DOI: 10.1023/A:1012982830367
关键词
canonical decomposition; dynamics; parallel factor analysis; proteins; relaxation; rotating frame; three-way decomposition
MUNIN ((Mu) under bar ltidimensional (N) under bar MR Spectra (In) under bar terpretation), a recently introduced approach exploiting the mathematical concept of three-way decomposition, is proposed for separation and quantitative relaxation measurements of strongly overlapped resonances in sets of heteronuclear two-dimensional spectra that result from typical relaxation experiments. The approach is general and may also be applied to sets of two-dimensional spectra with arbitrary modulation along the third dimension (e.g., J-coupling, diffusion). Here, the method is applied for the analysis of N-15 rotating frame relaxation data.
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