期刊
MONATSHEFTE FUR CHEMIE
卷 132, 期 11, 页码 1237-1268出版社
SPRINGER WIEN
DOI: 10.1007/s007060170016
关键词
ionic solvation; nonaqueous solutions; mixed solvents; preferential solvation; preferential solvation quotient
The history of studies on ionic solvation is briefly reviewed, and structural and dynamic properties of solvated ions in aqueous and nonaqueous solutions are discussed. An emphasis is placed on ionic solvation in nonaqueous mixed solvents in which preferential solvation of ions takes place. A new parameter for expressing the degree of preferential solvation of an ion is proposed.
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