期刊
ORGANIC LETTERS
卷 3, 期 24, 页码 3971-3974出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol016888t
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资金
- NIGMS NIH HHS [GM-29028] Funding Source: Medline
[GRAPHICS] In this, the second of two Letters, we describe an effective assembly of (+)-4, an eastern hemisphere subtarget comprising the FGH rings of (+)-nodulisporic acid A (1) (17 steps, 9% overall yield). Central to the synthesis is a Koga three-component conjugate addition-alkylation sequence which secures the trans orientation of the vicinal quaternary methyl groups.
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