4.7 Article

Solid polyelectrolyte (SPE) membranes containing a textured platinum catalyst

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JOURNAL OF MEMBRANE SCIENCE
卷 194, 期 1, 页码 135-140

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ELSEVIER SCIENCE BV
DOI: 10.1016/S0376-7388(01)00592-0

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ion-exchange membranes; membrane preparation and structure; platinum catalyst; electroless deposition

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Perfluorinated cation-exchange flat-sheet membranes were treated with cetyltrimethylammonium bromide surfactant (CH3(CH2)(15)N(CH3)(3)Br) to investigate the effect of the membranes modification with the surfactant on the morphology of deposition of a Pt catalyst. The electroless chemical deposition of a platinum catalyst onto the membranes treated with the surfactant was achieved by the Takenaka-Torikai method. The effect of the membranes modification on their electrical conductivity was studied. The morphology of the platinum micro-particles deposited onto the membranes modified with the surfactant was investigated by means of atomic force microscopy (AFM). (C) 2001 Elsevier Science B.V. All rights reserved.

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